Wednesday 8 May 2013

ISOMERISME

ISOMERISM

Existence of different compounds with the same molecular formula but different structural formular. Depend to branching of carbon and location of functional group.

ISOMERS

Different compounds that have same molecular formula

There are two types of isomers; 



      1. Chain Isomer  -  

       different arrangement in carbon atoms leading to linear and branched chain

      2. Positional Isomer -

the basic carbon skeleton remains unchanged, but the functional groups are moved around on that skeleton.





 




Isomerism in alkanes
              Molecular formula              Number of isomers                Structure name
                       CH4                   (no isomer)                     Methane
                      C2H6                   (no isomer)                      Ethane
                      C3H8                   (no isomer)                     Propane
                      C4H10                          2                     Butane
              2-methylpropane
                      C5H12                          3
          Pentane
            2-methylbutane 
           2,2-dimethylpropane


Isomerism in alkenes
 
              Molecular formula              Number of isomers                Structure name
                      C2H4                 (no isomer)                      Ethene
                      C3H6                 (no isomer)                      Propene
                      C4H8
3
But-1-ene
But-2-ene
2-methylpropene
                     C5H10
5
Pent-1-ene
Pent-2-ene
  2-methylbut-1-ene 
  3-methylbut-1-ene
  2-methylbut-2-ene








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